Funded Researchers & Collaborators

Prof Martin AlbrechtProfessor Martin Albrecht

UCD School of Chemistry and Chemical Biology

UCD Webpage

Molecular approaches to photolytic water splitting

Our research group aims at exploiting the wealth of activities of transition metals by appropriate ligand design. Applications range from molecular electronics, spintronics, and molecular switches up to anticancer activity. A large portion of our research activity is currently devoted to  the design, synthesis, and application of new catalytic systems. Recent interest includes, specifically, the use of so-called abnormal (mesoionic) carbene ligands, which combine a high donor power with the potential for cooperative ligand-metal processes. We have recently exploited these properties by devising base-free oxidation processes for alcohols and amines, and  we have developed a robust and active catalyst for water oxidation. 

Education & Appointments: 1996 M.Sc (Univ Bern, Switzerland)

                                                 2000 Ph.D (Utrecht Univ, The Netherlands; thesis advisor G. van Koten)

                                                 2001/2 Postdoc Fellow (Yale Univ; R. H. Crabtree)

                                                 2002/2003 Postdoc Fellow (Ciba SC; Basel)

                                                 2003-9 Assist Prof (Univ Fribourg, Switzerland)

                                                 since 2009, Full Prof UCD School of Chem & Chem Bio
Awards: 2003 A. Werner Assistant Professorship, 2008 ERC Starting Grant

Dr Teresa Curtin

Dr Teresa Curtin

Dept of Chemical and Environmental Sciences, University of Limerick
UL Webpage

Mesoporous solids for low temperature CO2 adsorption

Senior lecturer in the Materials and Surface Science Institute and Department of Chemical and Environmental Sciences; Course Director, Environmental Science.

Research is primarily focused on catalysis and adsorption using high surface area solids. Typical solids include mesoporous silica, aluminophosphates and aluminosilica type solids, zeolites and supported catalyst/adsorbents. Research includes synthesis and solid characterisation. These solids are primarily used for the adsorption of CO2 from air, removal of metals from water, oxidation of organics, oxidation of ammonia and the hydrogenation of edible oils.

Number of publications/awards/Professional bodies

  • Number of refereed journal publications: 24.
  • Book Chapters: 2.
  • Presentation at conferences: 30.
  • Funding Awarded to date: 1.1 million euro.
  • Nomination for best Excellence in Teaching Award 2008.
  • Member of Institute of Chemistry of Ireland (Fellow).

Some recent publications

  • Lenihan, S. and T. Curtin, 2009. ‘The Selective Oxidation of Ammonia Using Copper-based Catalysts: The Effects of Water’, Catalysis Today, 145 (1-2) 85-89.
  • O'Brien J., T. Curtin and T.F. O’Dwyer, 2008. ‘Removal of aniline from waste streams using a combined adsorption and catalytic oxidation approach’, Adsorption Science and Technology, 26 (5) 311-321.
Dr Denis Dowling

Dr Denis Dowling

UCD Schools of Electronic, Electrical and Mechanical Engineering & Chemical and Bioprocess Engineering
UCD Webpage

Fabrication of New Polymer-Titania Materials for more efficient PV Cells
Physical Vapour Deposition techniques in the synthesis of doped TiO2
Fabrication of nanocrystalline NiO surfaces

Photoelectrode fabrication and QD/Molecular Catalyst Immobilisation

Coated polymer substrates and Sealant

Denis has over 20 years experience in working in all aspects of materials science. He was responsible for setting up the Surface Engineering research group at Enterprise Ireland in 1990. He transferred this activity to UCD in 2004. The Group currently consists of over 20 researchers. Denis has managed a large number of both EU and industry funded research projects. His specialist areas of interest are in the use of plasma treatments for the surface modification of materials. Denis also has an IMI post graduate diploma in business strategy and has worked as a consultant assisting companies to develop their R&D activities. He has over 60 papers in peer reviewed journals, 40 other publications and 4 patents. He is the Irish representative on the COST Materials, Physical and Nanotechnology technical committee. He is also a member of the Irish branch of the Institute of Metal Finishing.

Dr Niall English

Dr Niall English

UCD School of Chemical & Bioprocess Engineering
UCD Webpage

Studies in Molecular and Electronic Modelling of Dye-sensitised and Semiconductor Nanorod PV Cells
Atomistic and quantum simulation of thin metal oxide films
Computational Analysis of the Active Site of Rubisco and Synthetic Analogues

Modelling of Hydrogen Storage and Release

Research

My interests focus on molecular and electronic-level modelling of: (i) the effects of electromagnetic and electric fields on (nano)materials and biological systems; (ii) solar energy materials design; (iii) water, ice and clathrate hydrate simulation; (iv) general applications of molecular simulation towards energy; and (v) computational nanoscience and nanomedicine. In so doing, my group and I employ and develop both classical and quantum molecular simulation techniques and codes. Five PhD students (co-supervised, two under my principal supervision), and one postdoctoral researcher. 30 articles in refereed international journals.

  • Committee member of the Nanoscale Simulators in Ireland (NSI), member of the Atlantic Centre for Atomistic Simulation (ACAM), and chair of the User’s Council of Irish Centre for High End Computing (ICHEC).
  • Co-organiser of curriculum and development of the NSI molecular simulation training initiative.
  • Experience in workshop/symposium organisation (NSI and CECAM).
  • Manager of SFI-funded HPC cluster for EMPS: grant, specification, procurement, system administration.
  • Associate member of Institution of Chemical Engineers (IChemE), member of American Institute of Chemical Engineers (AIChE) and American Chemical Society (ACS).

Dr Nick Gathergood

Dr Nick Gathergood

School of Chemical Sciences, Dublin City University
DCU Webpage

Applications of low toxicity and biodegradable ionic liquids

Research Interests:

  • Green Chemistry – New technologies to reduce environmental impact - ionic liquids for biomass manipulation and solar cells; atom economic synthesis; low toxicity and biodegradable solvents, reagents and catalysts
  • Chiral Technologies – catalysts, sensors, chiral recognition, chiral solvents
  • Medicinal Chemistry – ionophoric macrocyclic antibiotics, and p-gp inhibitors

Professional Bodies:

Society of Chemical Industry (SCI), Republic of Ireland Section, Chairman, 2007-2010.

Institute of Chemistry of Ireland, Fellow, 2007-

Royal Society of Chemistry (RSC), DCU and SCI ROI representative 2010-

EUCHEMs Organic Chemistry Division – Republic of Ireland representative and treasurer.

Chartered Chemist, Royal Australian Chemical Institute

Member, Society of Environmental Toxicology and Chemistry (SETAC) 2006- and Chemists in SETAC committee member 2007-

Postgraduate Supervision

4 PhDs graduated, Currently 9 PhD Researchers in team (2 co-supervised with Prof Stephen Connon, TCD)

Relevant Publications

  • Coleman, D. and Gathergood N. Biodegradation Studies of Ionic Liquids. Chemical Society Reviews, (2010), 39, 600-637.
  • Deng, Y; Morrissey, S.; Gathergood, N.; Delort, A.-M.; Husson, P.; and Costa Gomes, M. F. The Presence of Functional Groups Key for Biodegradation in Ionic Liquids: Effect on Gas Solubility. ChemSusChem, (2010), 3(3), 377-85.

  • Morrissey, S.; Pegot, B.; Coleman, D.; Garcia, M. T.; Ferguson, D.; Quilty, B.; Gathergood, N. Biodegradable, non-bactericidal oxygen-functionalised imidazolium esters: A step towards ‘greener’ ionic liquids. Green Chemistry, (2009), 11, 475-483.

Book Chapters

Ionic Liquids: Applications and Perspectives (Pub. InTech) February 2011. ISBN 978-953-307-248-7, (Ed.) Alexander Kokorin. Chapter Title. ‘Hydrogenation in Ionic Liquids’ Mukund Ghavre, Saibh Morrissey and Nicholas Gathergood, pp331-392

Patents

Gathergood, N.*; Pegot, B.; Beadham, I.; Gurbisz, M.; Ghavre, M.; Morrissey, S. Ionic Liquid Solvents. EPO patent application 09002653.5, 2009, filed 25th February 2009. PCT/EP2010/052345 (WO/2010/097412) filed 24th February 2010.

Gathergood, N.*; Pegot, B.; Morrissey, S. Biodegradable Solvents for the Chemical Industry: Task Specific ionic liquids, Irish patent application, 2007/0597 filed 21st August 2007. PCT Int. Appl. PCT/EP2008/060978 filed 6th September 2008. National phase Feb 2010.

Dr Chandralal Hewage

Dr Chandralal Hewage

UCD School of Biomolecular & Biomedical Science
UCD Webpage

Main Group Metal Analogues of the Catalytic Site in Rubisco

Research Focus

  • Structural studies of incretin peptide hormones.
  • New catalysts, Rubisco and renewable energy.
  • NMR investigations of antimicrobial peptides.
  • Protein-ligand docking studies of Class-B GPCR receptors.
  • Natural products for diabetic therapy.
  • Bio-actives and Natural beverages.

Number of publications/awards/professional bodies

  • Over hundred publications and communications.
  • Award from the Enterprise Ireland, Science Foundation Ireland, IRCSET, Teagasc, UCD.
  • Chairman of the Irish NMR Society.
  • Secretary of the Irish Peptide Society.
  • Board Member – EU NMR Society (EUROMAR).
  • Board Member – EU Peptide Society (EPS).
Prof J.Paul.G. Malthouse

Professor J. Paul. G Malthouse

UCD School of Biomolecular & Biomedical Science
UCD Webpage

Main Group Metal Analogues of the Catalytic Site in Rubisco

Research

Currently we are synthesizing specific glyoxal inhibitors. These we hope will be lead compounds in developing new drugs to treat conditions such as cancer, malaria, diabetes and Alzheimer's disease. We are also studying biomimetic methods of carbon dioxide fixation. A range of metals, metal scaffolds and substrates will be assessed as possible biomimetics using NMR and other techniques.

221 Publications to date (95 research articles, 7 review articles, 2 published lectures, 117 posters/abstracts). H-index = 22.

Awards & Honours

  • 1990: President's Research Fellowship for a project entitled "13C NMR as a probe of enzyme mechanisms".
  • National Committee for Biochemistry Award Medal for 1997.
  • In 2005 elected a member of the Royal Irish Academy.
  • In 2008: President's Research Fellowship for a project entitled "Optimising protease inhibition and developing biomimetic methods for carbon dioxide fixation".

Professional Bodies

  • 2005-present, Irish expert on the EU COST Technical Committee for Chemistry.
  • Editor for Enzyme Research (http://www.sage-hindawi.com/journals/er/).
  • Editorial Advisor for Biochemical Journal since 1997.
  • Referee for JACS, Biochemistry, BBA, Protein Science, FEBS letters.
  • Member of Royal Irish Academy, Biochemical Society, International Proteolysis Society and European Peptide Society.

Dr Damian A Mooney

UCD School of Chemical and Bioprocess Engineering
UCD Webpage

Studies in Molecular and Electronic Modelling of Dye-sensitised and Semiconductor Nanorod PV Cells
Computational Analysis of the Active Site of Rubisco and Synthetic Analogues

Research

  • Molecular simulation (classical, quantum), transport processes, porous media, soft matter, protein structure/function.
  • 32 refereed publications to date (6 in 2009), Awards from EU FP6, Science Foundation Ireland, Enterprise Ireland.

Awards

  • Institute of Chemical Engineers (UK), Student Award (1990).
  • Du Pont Research Scholarship, 3 years (1992-1995).
  • Forbairt Research Award (1992-1995).
  • BOC Gases Research Award (1994).
  • Bayer Postdoctoral Fellowship (1996, 1997).
  • Royal Academy of Engineering (UK) Travel Award (2003).
  • UCD Presidents Research Award (2004).
  • Short-Term Travel Fellowship, SFI (2009).
  • President’s Research Fellowship (2009).

Professional Bodies

  • Member of the American Institute of Chemical Engineers.
Dr Grace Morgan

Dr Grace Morgan

UCD School of Chemistry and Chemical Biology
UCD Webpage

Transition Metal Analogues of the Catalytic Site in Rubisco

Molecular catalysts for CO2 Reduction/ Photo-electrochemical Cells for water-splitting and CO2 Reduction

Academic Appointments

  • Sep 2001- present: College Lecturer, Department of Chemistry, UCD
  • Jan 2000-Sep 2001: Assistant Lecturer, UCD
  • 1999-2000: Postdoctoral researcher, Max Planck Institut für Strahlenchemie, Mülheim an der Ruhr, Germany.
  • 1996-1999: Instructor in Inorganic Chemistry, Queen’s University, Belfast.
  • 1995-1996: Postgraduate Certificate in Education, Queen’s University, Belfast.
  • 1991-1995: PhD in Coordination Chemistry, The Open University (with Prof Jane Nelson, Belfast).
  • 1994: Chartered Chemist status (CChem) awarded by the Royal Society of Chemistry.

Postgraduate Supervision

  • Completed: Caroline Murray (PhD), 2007, Stephen Shakespeare (MSc), 2006, Kevin Murnaghan (PhD), 2005, Caroline Murray (MSc), 2003.
  • Current: Michael Griffin (IRCSET), Laurence Gavin (UCD Funding), Paulo Nuno Martinho (ERA-Chemistry), Komala Pandurangan (IRCSET), Brendan Gildea (IRCSET), Kevin Fennell (SFI), Michelle Harris (UCD Funding).

Relevant Publications

  • Improved Cooperativity of Spin-Labile Iron(III) Centers by Self-Assembly in Solution, Claudio Gandolfi, Christian Moitzi, Peter Schurtenberger, Grace G. Morgan and Martin Albrecht, J. Am. Chem. Soc., 2008, 130, 14434.
  • A Manganese(III) Complex that Exhibits Spin Crossover Triggered by Geometric Tuning, G. G. Morgan, K. D. Murnaghan, H. Muller-Bunz, V. McKee and C. J. Harding, Angew. Chem. Int. Ed., 2006, 45, 7192.
  • d10 Cations within Triple-Helical Cryptand hosts; a Structural and Modelling Study, M. G. B. Drew, D. Farrell, G. G. Morgan, V. McKee and J. Nelson, J. Chem. Soc., Dalton Trans., 2000, 1513.
  • Encapsulated Tl(III) Strongly Retained within an Inminophenolate Cryptand host, M. G. B. Drew, O. W. Howarth, N. Martin, G. G. Morgan and J. Nelson, J. Chem. Soc., Dalton Trans., 2000, 1275.

Dr Andrew Phillips

Dr Andrew Phillips

UCD School of Chemistry and Chemical Biology

Science Foundation Ireland (SFI) Stokes lecturer of Inorganic Chemistry, appointed Autumn 2008

UCD Webpage

Synthesis and optimisation of metal-based solar dye complexes

Hydrogen Release Catalysis

 

Our research is directed towards the design and synthesis of highly electronically tuneable ruthenium and cobalt complexes based on new pi-conjugated chelating azo-substituted heterocycles.   We routinely employ high-level DFT calculations to help optimize the nature of the complex and ligand in terms of absorption wavelength and control of the metal-to-ligand charge transfer.  We specialize in techniques where the complexes can be prepared in large quantities without the need of using advanced and time consuming chromatographic separation methods.   Dr. Phillips is the author of over 60 papers in international journals and has one patent in the area of hydrogen storage. He has a broad international research background, having studied and worked in Canada (Ph.D. 2001), United States, Italy, France, Spain (European Network Fellowship) and Switzerland (Marie Curie Fellowship).  He is a member of the Swiss, Canadian and American Chemistry Societies.  Currently the UCD research group consists of two graduate students and one post-doctoral fellow.

Dr Mary Pryce

School of Chemical Sciences, Dublin City Univeristy

DCU Webpage

Molecular catalysts for CO2 Reduction/ Photo-electrochemical Cells for water-splitting and CO2 Reduction

BSc. degree from DCU in 1991. A PhD (1991-1994) was subsequently obtained in organometallic photochemistry. Post doctoral studies were carried out during 1995 and 1996 at the University of Milan with Prof. Stefano Maiorana before rejoining the School of Chemical Sciences at DCU in 1997 as a Lecturer.

Research Interests: organometallic photochemistry, photophysics, spectroscopy, and the uses of organometallic compounds in organic synthesis

 

Dr Kevin M Ryan

Dr Kevin M. Ryan

Dept of Chemical and Environmental Sciences, University of Limerick
http://ifnano.com

Directed Vertical Assembly of II-VI Semiconductor Nanorods for Low-Cost Solution Processable Solar Cells

Synthetic Protocols for Nanorod Crystals

The Nanotechnology group at the Materials and Surface Science Institute is led by Dr. Kevin M. Ryan, SFI Stokes Lecturer, Department of Chemical and Environmental Sciences. Previous affiliations included Marie Curie Fellowship positions at the University of California, Berkeley, USA and Merck Chemicals Southampton, UK following BSc (99) and PhD degrees (03) at University College Cork.

The research Interests of the group (currently 4 Postdoctoral researchers and 6 PhD students) are in Semiconductor Nanocrystals with emphasis on Synthesis, Assembly and Device Application. Funding is Gratefully Acknowledged from Science Foundation Ireland (SFI), for both a Principal Investigator Grant and Strategic research cluster funding and also to Enterprise Ireland (EI), Irish Research Council for Science Engineering and Technology (IRCSET), Higher Education Authority (HEA) and Intel Ireland.

  • >32 Publications, 1 Patent, 1 book Chapter, > 400 Citations
  • Institute of Chemistry of Ireland Golden Jubilee Award 2001
  • Member of Royal Society of Chemistry, Materials Research Society, Electrochemical Society, Marie Curie Fellowship Association
Prof Cosima Stubenrauch

Professor Cosima Stubenrauch

UCD School of Chemical and Bioprocess Engineering & Institute of Physical Chemistry, University Stuttgart, Germany
UCD Webpage

Synthesis and Characterisation of New High Surface Area Polymers

1997 PhD in Physical Chemistry (TU Berlin, Germany), 1998-1999 post-doc (Paris, France), 1999-2004 associate researcher and lecturer (Cologne, Germany), 2004 Habilitation in Physical Chemistry, 2005-2007 lecturer at UCD, 2007-2009 senior lecturer at UCD, since 2009 Visiting Professor at UCD and Chair of Physical Chemistry at University Stuttgart, Germany.

11 prestigious awards and fellowships. Research activities: 89 publications including 7 invited reviews and 6 book articles, 1 book edited, 93 lectures (31 conference contributions (13 invited talks), 56 invited seminars, and 6 presentations at industrial companies). Various international cooperations, co-ordination of a Marie Curie RTN (SOCON), total fund raising of 4.7 Mio € (1.8 Mio € for own research). Further details on weblink above.

Dr James A Sullivan

Dr James Sullivan

UCD School of Chemistry and Chemical Biology
UCD Webpage

Sol-gel synthesis and characterisation of the photo-electrochemical activity of doped TiO2
Transition Metal Analogues of the Catalytic Site in Rubisco

Hetrogenization and reversible Hydrogen Release Catalysis

BSc (1992), PhD, unfder the supervision of Prof J Cunningham (1996) UCC, Post doctoral research fellow University of Reading (1996-1999), Honorary research fellow QUB (1999-2000), Appointed to UCD in 2000, Senior Lecturer(2007), School Head of Teaching and Learning.

Research Interests

  • Environmental Heterogeneous Catalysis with projects including Particulate Matter Combustion and NOx Storage and Reduction using Pt/Ba Al2O3 catalysts.
  • Biodiesel Synthesis using heterogeneous acid / base catalysts.
  • Selective Glycerol Oxidation using supported Au nanoparticles
  • CO2 fixation using H2, H2O splitting using photo-catalysts
  • Selective oxidation using in-situ generated H2O2

The group currently has 5 PhD students and a post-doctoral fellow and has graduated 2 PhDs and an MSc by research.

Publications

  • 25 publications in peer reviewed literature.
  • 30 presentations and invited lectures at international conferences.
  • H-factor of 10, MRSC, MICI, Member of supervisory board of ACENET and council of EFCATS.
  • External referee for EU transnational grant at CenTACat QUB.
  • External examiner to BSc degree DIT.
Prof K. Ravi Thampi

Professor K. Ravindranathan Thampi

Science Foundation Ireland-Airtricity Professorship (Associate) in Solar Energy Engineering

UCD School of Chemical and Bioprocess Engineering
UCD Webpage

Dye Sensitized Solar Cells; Q-dots; Cell design and Architecture

Photolysis & Photocatalysis

Before joining UCD in July 2009, he was a group leader and Project Manager at the Laboratory of Photonics & Interfaces (LPI), EPFL, Lausanne, Switzerland, where he worked for over 23 years and intimately followed the invention and development of dye sensitized solar cells from their inception. He has extensive collaborations with several countries, notably EU countries, USA, India and Japan.

Besides his teaching and research activities, he directs and manages many research projects funded by various national and international institutions.

Research

  • Catalysis, fuel cells, nanomaterials, solar cells, and photoelectrochemical water splitting. Some of his inventions have been commercially applied and licensed to industries.
  • He has published about 90 research papers on solar energy, photocatalysis, heterogeneous catalysis, solid state chemistry, fuel cells and biosensors in top international journals and books.
  • He is an Associate Editor of the ASME Journal of Fuel Cell Science and Technology.
  • He is also an Editorial Board Member of IJoMS (International Journal of Materials Science).
  • He has about ten patents to his credit. He was the international co-ordinator of the ISCB biosensor development project funded jointly by the Swiss and Indian governments, which has now reached the commercial prototype stage (licensed to industry).
  • His past industrial experience includes the scaling up of a laboratory invention in catalysis to a large commercial petrochemical plant.
  • He has expertise in IP management and assisting industrial start-ups.
  • Previously a member of the IEA SOFC annexe panel for making standards for electrochemically testing solid oxide fuel cells.
Dr Dominic Zerulla

Dr Dominic Zerulla

UCD School of Physics
UCD Webpage

Spectroscopy and Efficacy of Dye Sensitized Solar Cells; Imaging and Spectroscopy of the Wide Band-Gap II-VI Nanorod PV Cells

Plasmonic Enhancement of Q-dot Cells

Dr. Zerulla is the founding member and leader of the UCD Molecular Biophysics – Imaging and Spectroscopy at the Nanoscale group since his arrival in UCD in October 2004. He is Senior Lecturer at the UCD School of Physics and Fellow of the Institute of Physics (IOP). Previously, he was the leader of the Biophotonics group at the Heinrich-Heine-University in Düsseldorf, Germany, and has also worked at the Astrakhan State University, Russia where he was a visiting Professor for Advanced Optics.

His current research projects, which are supported by a number of SFI grants, are in ultra fast laser spectroscopy, plasmonics, non-linear optics, nano optics and novel solar cell research..